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Interphase catalysis in Michael and Knoevenagel reactions with α,β-unsaturated aldehydes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Dry Na2CO3 in the presence of TEBA was used to generate carbanions from malonic and acetoacetic esters.

  2. 2.

    The thus generated carbanions undergo Michael addition to acrolein, crotonaldehyde, cinnamaldehyde, and the dimethyl manoacetal of fumaric dialdehyde, but undergo Knoevenagel condensation with citral.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    G. V. Kryshtal', V. V. Kul'ganek, V. F. Kucherov & L. A. Yanovskaya

Authors
  1. G. V. Kryshtal'
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  2. V. V. Kul'ganek
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  3. V. F. Kucherov
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  4. L. A. Yanovskaya
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2808–2811, December, 1978.

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Kryshtal', G.V., Kul'ganek, V.V., Kucherov, V.F. et al. Interphase catalysis in Michael and Knoevenagel reactions with α,β-unsaturated aldehydes. Russ Chem Bull 27, 2508–2510 (1978). https://doi.org/10.1007/BF00941112

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  • DOI: https://doi.org/10.1007/BF00941112

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