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Synthesis of α-mercaptobenzhydryldiphenylphosphine and some of its properties

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

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Conclusions

Diphenylphosphine reacts with thiobenzophenone to giveα-mercaptobenzhydryldiphenylphosphine, which is rearranged by heat to benzhydryldiphenylphosphine thiooxide, whereas rearrangement in conc. HCl leads to benzhydryldiphenylphosphine oxide.

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Literature cited

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch of the Academy of Sciences of the USSR, USSR

    A. N. Pudovik, G. V. Romanov & V. M. Pozhidaev

Authors
  1. A. N. Pudovik
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  2. G. V. Romanov
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  3. V. M. Pozhidaev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2800–2802, December, 1978.

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Pudovik, A.N., Romanov, G.V. & Pozhidaev, V.M. Synthesis of α-mercaptobenzhydryldiphenylphosphine and some of its properties. Russ Chem Bull 27, 2500–2501 (1978). https://doi.org/10.1007/BF00941108

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  • DOI: https://doi.org/10.1007/BF00941108

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