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Polarizability anisotropy and steric structure of aryl thiocyanates

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The polarizability parameters of the thiocyanate group were determined.

  2. 2.

    Phenyl thiocyanate has a planar conformation in solution. Its derivatives, with donor substituents in the p position of the ring, are characterized by a nearly coplanar arrangement of SCN and the ring. Acceptor substituents facilitate a withdrawal of the system from the plane.

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Literature cited

  1. I. V. Isakov and Z. V. Zvonkova, Kristallografiya,10, 194 (1965).

    Google Scholar 

  2. I. V. Isakov and Z. V. Zvonkova, Kristallografiya,14, 696 (1969).

    Google Scholar 

  3. E. G. Yarkova, N. R. Safiullina, G. A. Chmutova, and I. V. Bautina, Zh. Obshch. Khim.,48 (1978).

  4. I. V. Isakov, E. É. Rider, and Z. V. Zvonkova, Kristallografiya,22, 1086 (1977).

    Google Scholar 

  5. G. A. Chmutova, I. V. Bautina, and A. N. Vereshchagin, Izv. Akad. Nauk SSSR, Ser. Khim., 2469 (1976).

  6. D. G. Lister, J. K. Tyler, J. H. Hogg, and N. Wessel Larsen, J. Mol. Struct.,23, 253 (1974).

    Google Scholar 

  7. L. V. Vilkov and T. P. Timasheva, Dokl. Akad. Nauk SSSR,161, 351 (1965).

    Google Scholar 

  8. T. W. Campbell and M. T. Rogers, J. Am. Chem. Soc.,70, 1029 (1948); G. A. Chmutova, L. A. Sorokina, A. M. Kataeva, and N. S. Podkovyrina, Zh. Fiz. Khim.,48, 282 (1974).

    Google Scholar 

  9. G. Ya. Cheryukanova, Dissertation, Kazan (1974).

  10. P. H. Gore, P. A. Hopkins, R. J. W. Le Fevre, L. Radom, and G. L. D. Ritchie, J. Chem. Soc. B, 120 (1971).

    Google Scholar 

  11. S. Nakagawa, T. Kojima, S. Takahashi, and C. Lin Chun, J. Mol. Spectrosc.,14, 201 (1964).

    Google Scholar 

  12. N. I. Sadova, N. P. Penionzhkevich, and L. V. Vilkov, Zh. Strukt. Khim.,17, 1122 (1976).

    Google Scholar 

  13. N. N. Mel'nikov and N. D. Sukhareva, in: Reactions and Methods for Study of Organic Compounds [in Russian], Vol. 8, Moscow (1959), p. 55.

    Google Scholar 

  14. A. N. Vereshchagin and L. A. Grozina, Teor. Eksp. Khim.,4, 361 (1968).

    Google Scholar 

  15. B. A. Arbuzov, A. N. Vereshchagin, and S. G. Vul'fson, Monograph on Some Problems in Organic and Physical Chemistry [in Russian], IOFKh AN SSSR, Kazan (1972), p. 228.

    Google Scholar 

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch of the Academy of Sciences of the USSR, USSR

    I. V. Bautina, G. A. Chmutova & A. N. Vereshchagin

  2. V. I. Ul'yanov-Lenin Kazan State University, USSR

    I. V. Bautina, G. A. Chmutova & A. N. Vereshchagin

Authors
  1. I. V. Bautina
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  2. G. A. Chmutova
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  3. A. N. Vereshchagin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2792–2794, December, 1978.

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Bautina, I.V., Chmutova, G.A. & Vereshchagin, A.N. Polarizability anisotropy and steric structure of aryl thiocyanates. Russ Chem Bull 27, 2492–2494 (1978). https://doi.org/10.1007/BF00941105

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  • DOI: https://doi.org/10.1007/BF00941105

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