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Synthesis of cyclobutane derivatives by codimerization of conjugated dienes with ethylene using catalysts based on titanium monocyclopentadienyl compounds

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The codimerization of either 1,3-butadiene or 1,3-pentadiene with ethylene in the presence of the catalyst system C5H5Ti[OSi(CH3)3]3-CH3MgI assures the selective synthesis of vinylcyclobutanes.

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Literature cited

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2781–2783, December, 1978.

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Vdovin, V.M., Amerik, A.B. & Poletaev, V.A. Synthesis of cyclobutane derivatives by codimerization of conjugated dienes with ethylene using catalysts based on titanium monocyclopentadienyl compounds. Russ Chem Bull 27, 2482–2484 (1978). https://doi.org/10.1007/BF00941101

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  • DOI: https://doi.org/10.1007/BF00941101

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