Conclusions
The codimerization of either 1,3-butadiene or 1,3-pentadiene with ethylene in the presence of the catalyst system C5H5Ti[OSi(CH3)3]3-CH3MgI assures the selective synthesis of vinylcyclobutanes.
Literature cited
A. B. Amerik, V. M. Vdovin, and V. A. Poletaev, Izv. Akad. Nauk SSSR, Ser. Khim., 167 (1977).
V. M. Vdovin, A. B. Amerik, and V. A. Poletaev, Neftekhimiya,17, 518 (1977).
L. Cannel, Ann. N. Y. Acad. Sci.,214, 143 (1973).
R. Srinivasan and K. A. Hill, J. Am. Chem. Soc.,87, 4988 (1965).
O. A. Aref'ev, V. A. Zakharenko, and A. A. Petrov, Neftekhimiya,4, 854 (1964).
A. N. Nesmeyanov and K. A. Kocheshkov (editor), Methods in Heteroorganic Chemistry [in Russian], Vol. 1, Nauka (1974), p. 179.
A. N. Nesmeyanov, O. V. Nogina, A. M. Berlin, A. S. Grishovich, and G. V. Shatalov, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk,12, 2146 (1961).
R. D. Gorsich, J. Am. Chem. Soc.,82, 4211 (1960).
T. Chivers and E. D. Ibrahim, J. Organomet. Chem.,77, 241 (1974).
R. G. Miller, T. J. Kealy, and A. L. Barney, J. Am. Chem. Soc.,89, 3756 (1967).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2781–2783, December, 1978.
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Vdovin, V.M., Amerik, A.B. & Poletaev, V.A. Synthesis of cyclobutane derivatives by codimerization of conjugated dienes with ethylene using catalysts based on titanium monocyclopentadienyl compounds. Russ Chem Bull 27, 2482–2484 (1978). https://doi.org/10.1007/BF00941101
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DOI: https://doi.org/10.1007/BF00941101