Summary
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1.
Methods have been developed for obtaining o-mercapto sulfones of the benzene, naphthalene, and thiophene series, and derivatives with transition-metal salts have been obtained for them.
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2.
The presence of an intramolecular hydrogen bond in the o-mercapto sulfones has been shown by IR spectroscopy, and spectral confirmation has been shown of the participation of the sulfonyl group in coordination with the metal in their metal derivatives.
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3.
A number of o-bissulfones and trissulfones of the benzene and thiophene series have been synthesized. The basic possibility of nucleophilic substitution of one of the sulfone groups in them has been shown.
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Literature cited
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For Communication 12, see [1].
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2760–2767, December, 1978.
The authors express their gratitude to I. P. Yakovlev for a discussion of the spectral results.
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Gol'dfarb, Y.L., Stoyanovich, F.M., Chermanova, G.B. et al. Reactions of arylsulfonyl compounds with an excess of an organolithium reagent 13. Synthesis of o-mercapto sulfones and o-bissulfones of the benzene, naphthalene, and thiophene series from o-lithio sulfones. Russ Chem Bull 27, 2462–2469 (1978). https://doi.org/10.1007/BF00941097
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DOI: https://doi.org/10.1007/BF00941097