Conclusions
-
1.
The oxides of lanthanum, neodymium, samarium, gadolinium, dysprosium, erbium, and yttrium are active in the hydrogen transfer from n-butanol to dipropylketone and acetone and from 2-octanol to eyclohexanone; the latter reaction is most selective.
-
2.
The comparative reactivities of the ketonic hydrogen acceptors in the reaction of these compounds with n-butanol is in accord with their normal oxidation potentials.
-
3.
Upon the addition of ketone to n-butanol, the total extent of the catalytic conversion of n-butanol increases and the selectivity relative to ketonization decreases.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
M. Padoa and B. Foresti, Atti Accad. Lincei,23, II, 84 (1914); Chem. Abstr.,9, 736 (1915).
S. Malinowski and T. Kobyliński, Actes du deuxième Congrès International de Catalyse, Paris, 1960, Editions Technique, Paris (1961), p. 2689.
C. H. Milligan and E. E. Reid, J. Am. Chem. Soc.,44, 202 (1922).
S. Ballard, H. Finch, and D. Winkler, in: Catalysis, Abstracts of the First International Congress [Russian translation], IL (1960), p. 849.
Z. Gryaznova, G. Epishina, and K. Baskunyan, Izv. Otd. Khim. Nauk. Bulg. Akad. Nauk,6, No. 2, 431 (1973).
L. Kh. Freidlin, V. Z. Sharf, E. N. German, N. K. Vorob'eva, and S. I. Shcherbakova, Izv. Akad. Nauk SSSR, Ser. Khim., 2130 (1970).
O. V. Krylov and E. A. Fokina, in: Fundamentals of Predicting Catalytic Activity, Abstracts of the Fourth International Congress on Catalysis, Vol. 2, [in Russian], Nauka (1970), p. 221.
Kh. M. Minachev, Yu. S. Khodakov, G. V. Antoshin, and M. A. Markov, The Rare Earths in Catalysis [in Russian], Nauka (1972), p. 172.
H. Adkins, R. M. Elofson, A. G. Rossow, and C. C. Robinson, J. Am. Chem. Soc.,71, 3622 (1949).
Kh. M. Minachev, O. K. Atal'yan, and M. A. Markov, Izv. Akad. Nauk SSSR, Ser. Khim., 2731 (1978).
J. G. M. Bremner and G. D. Thomas, Trans. Faraday Soc.,44, No. 5, 230 (1948).
D. Stahl, E. Westrum, and G. Zinke, The Chemical Thermodynamics of Organic Compounds [Russian translation], Mir (1971), p. 465.
G. A. Loginov, Dissertation, Moscow (1968).
Author information
Authors and Affiliations
Additional information
Deceased.
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2737–2743, December, 1978.
Rights and permissions
About this article
Cite this article
Minachev, K.M., Atal'yan, O.K. & Markov, M.A. The hydrogen transfer reaction on oxides of the rare-earth elements. Russ Chem Bull 27, 2442–2447 (1978). https://doi.org/10.1007/BF00941093
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00941093