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Hydrogen bonds in γ-oxyphosphoryl compounds

  • E. P. Trutneva
  • R. R. Shagidullin
  • L. V. Stepashkina
  • N. I. Rizpolozhenskii
Physical Chemistry
  • 14 Downloads

Conclusions

  1. 1.

    The tendency toward formation of intermolecular self-associates through the P=O... H-O H bonding is less pronounced in theγ-oxyphosphoryl compounds than in theα- andβ-analogs.

    The strength of the intramolecular H bonding between these same functional groups increarses with the size of the closed five- and seven-membered rings.

     
  2. 2.

    In distinction to the five-membered rings of theα-oxyphosphoryl compounds, the seven-membered rings of theγ-analogs closed with P=O... H-O IHB are more stable than the corresponding rings closed with P=S... H-O IHB.

     

Keywords

Hydrogen Hydrogen Bond 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1979

Authors and Affiliations

  • E. P. Trutneva
    • 1
  • R. R. Shagidullin
    • 1
  • L. V. Stepashkina
    • 1
  • N. I. Rizpolozhenskii
    • 1
  1. 1.A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan BranchAcademy of Sciences of the USSRUSSR

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