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Luminol oxidation with chemiluminescence 6. The mechanism of chemiluminescence of the luminol-CNO2)4-H2O2 system

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A mechanism describing the quantitative aspects of the chemiluminescence in the interaction of luminol with tetranitromethane in the presence of H2O2 has been proposed. The particles responsible for the chemiluminescence are active intermediates resulting from reaction of H2O2 with the tetranitromethane.

  2. 2.

    This mechanism has been used to calculate rate constant ratios for reaction of the intermediate with luminol and hydrogen peroxide, and for reaction of the intermediate with luminol and tetranitromethane.

  3. 3.

    The yield of the intermediate which oxidizes the LH2 is 0.5. Yields have been calculated for the excited particles produced in the formation of the emitter.

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Literature cited

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    T. P. Vorob'eva, Yu. N. Koztov, Yu. V. Koltypin, A. P. Purmal' & B. A. Rusin

Authors
  1. T. P. Vorob'eva
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  2. Yu. N. Koztov
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  3. Yu. V. Koltypin
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  4. A. P. Purmal'
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  5. B. A. Rusin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2715–2718, December, 1978.

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Vorob'eva, T.P., Koztov, Y.N., Koltypin, Y.V. et al. Luminol oxidation with chemiluminescence 6. The mechanism of chemiluminescence of the luminol-CNO2)4-H2O2 system. Russ Chem Bull 27, 2423–2426 (1978). https://doi.org/10.1007/BF00941089

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  • DOI: https://doi.org/10.1007/BF00941089

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