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Activation of molecular hydrogen by transition metal complexes 1. Autocatalysis in the hydrogenation of [PPh3Pd(OAc)2]2

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reaction ofμ-diacetatediacetatoditriphenylphosphinedipalladium with hydrogen is an autocatalytic process.

  2. 2.

    The length of the induction period for this process depends on the nature of the solvent; it is unaffected by the introduction of acetic acid into the system, and increases with falling concentration of complex or hydrogen, or with rising concentration of the triphenylphosphine.

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Literature cited

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow

    A. S. Berenblyum, A. G. Knizhnik, S. L. Mund & I. I. Moiseev

  2. Elektrogorsk Branch, All-Union Scientific-Research Institute for Petroleum Processing, USSR

    A. S. Berenblyum, A. G. Knizhnik, S. L. Mund & I. I. Moiseev

Authors
  1. A. S. Berenblyum
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  2. A. G. Knizhnik
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  3. S. L. Mund
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  4. I. I. Moiseev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2711–2715, December, 1978.

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Berenblyum, A.S., Knizhnik, A.G., Mund, S.L. et al. Activation of molecular hydrogen by transition metal complexes 1. Autocatalysis in the hydrogenation of [PPh3Pd(OAc)2]2 . Russ Chem Bull 27, 2419–2422 (1978). https://doi.org/10.1007/BF00941088

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  • DOI: https://doi.org/10.1007/BF00941088

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