Skip to main content
SpringerLink
Log in

Transition metal complexes of 2-Carbethoxypyridine (Ethyl picolinate)

  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Summary

A variety of metal(II) complexes of 2-carbethoxypyridine (L) have been prepared and characterised. With metal(II) chlorides the bis complexes can be formulated [ML2Cl2]o (M=CuII, NiII, CoII, FeII or MnII). The complexes are six-coordinate with 2-carbethoxypyridine acting as a bidentate ligandvia the pyridine nitrogen and the carbonyl group of the ester. The chloro complexes are nonelectrolytes in nitroethane; magnetic susceptibility measurements, i.r. and d-d electronic spectra are reported. With metal(II) perchlorate salts the complexes can be formulated as six-coordinate [ML2 (OH2)2] [ClO4]2 species containing ionic perchlorate. The ester exchanges of some of these complexes with a variety of primary alcohols have been investigated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M. P. Springer and C. Curran,Inorg. Chem., 2, 1270 (1963).

    Google Scholar 

  2. H. Shindo and L. T. Brown,J. Am. Chem. Soc., 98, 1904 (1965).

    Google Scholar 

  3. R. W. Hay and L. J. Porter,Aust. J. Chem., 20, 675 (1967).

    Google Scholar 

  4. J. K. H. Ma, J. T. Wang and N. C. Li,J. Coord. Chem., 2, 281 (1973).

    Google Scholar 

  5. Kh. Kh. Khakimov, M. A. Azivov and K. S. Khakimova,Zh. Neorg. Khim., 16, 128 (1971).

    Google Scholar 

  6. A. Agren,Acta Pharm. Suecicca, 2, 87 (1965).

    Google Scholar 

  7. D. St. C. Black and R. Srivasta,Aust. J. Chem., 23, 2067 (1970).

    Google Scholar 

  8. W. Ludwig and F. Gasser,Helv. Chim. Acta, 52, 2380 (1969).

    Google Scholar 

  9. Kh. Kh. Khakimov, M. A. Azivov and K. M. Kantsepolskaya,Zh. Neorg. Khim., 15, 2173 (1970).

    Google Scholar 

  10. Kh. Kh. Khakimov, M. A. Azivov and K. M. Kantsepolskaya,Zh. Strukt. Khim., 11, 859 (1970).

    Google Scholar 

  11. R. C. Paul, R. S. Chopra, R. K. Bhambri and G. Singh,J. Inorg. Nucl. Chem., 36, 3703 (1974).

    Google Scholar 

  12. R. C. Paul, R. S. Chopra and G. Singh,Inorg. Chim. Acta, 14, 105 (1975).

    Google Scholar 

  13. E. K. Barefield, D. H. Busch and S. M. Nelson,Quart. Rev., 22, 457(1968).

    Google Scholar 

  14. A. G. Carty,Can. J. Chem., 45, 345 (1967).

    Google Scholar 

  15. R. W. Hay,Aust. J. Chem., 17, 759 (1964).

    Google Scholar 

  16. R. W. Hay,Aust. J. Chem., 20, 1829 (1967).

    Google Scholar 

  17. J. A. Bertrand and D. Caine,J. Am. Chem. Soc., 86, 2298 (1964).

    Google Scholar 

  18. R. P. Houghton and C. S. Williams,Tetrahedron Lett., 5091 (1967).

  19. R. Levine and J. K. Sneed,J. Am. Chem. Soc., 73, 5615 (1951).

    Google Scholar 

  20. M. Samejima,Yakugaku Zasshi, 80, 1706 (1960).

    Google Scholar 

  21. B. J. Hathaway and A. E. Underbill,J. Chem. Soc., 3091 (1961).

Download references

Author information

Authors and Affiliations

  1. Chemistry Department, University of Stirling, FK9 4LA, Stirling, Scotland

    Robert W. Hay & Charles R. Clark

Authors
  1. Robert W. Hay
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Charles R. Clark
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Hay, R.W., Clark, C.R. Transition metal complexes of 2-Carbethoxypyridine (Ethyl picolinate). Transition Met Chem 4, 28–31 (1979). https://doi.org/10.1007/BF00941012

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00941012

Keywords

Search

Navigation