Abstract
A new preparative route for silyl esters is described, involving reaction of silyl bromide and trisalkyltin esters. The far infrared spectrum of some simple esters are reported; an investigation of the shifts in the carbonyl stretching band on condensation shows no significant differences in behaviour between methyl and silyl esters.
Zusammenfassung
Es wird ein neuer präparativer Weg (über Silylbromid und Trisalkylzinnester) für die Synthese von Silylestern beschrieben. Das ferne IR einiger Ester wird angeführt; eine Untersuchung der Verschiebung der Carbonyl-Streck-Frequenz bei Kondensation zeigt keine signifikanten Unterschiede zwischen Methyl- und Silyl-Estern.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
E. A. V. Ebsworth, J. C. Thompson, J. Chem. Soc. (A)1967, 69.
R. A. Cummins andP. Dunn, Aust. J. Chem.17, 185 (1964).
A. G. Robiette andJ. C. Thompson, Spectrochim. Acta21, 2023 (1965).
S. Cradock, E. A. V. Ebsworth, andH. F. Jessep, J. Chem. Soc. (Dalton)1972, 359.
P. C. Angus andS. R. Stobart, J. Chem. Soc. (Dalton)1975, 2342.
W. Bett, S. Cradock, andD. W. H. Rankin, J. Mol. Structure, submitted for publication.
M. Barrow, W. Bett, S. Cradock, andD. W. H. Rankin, J. Chem. Soc. (Dalton), submitted for publication.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Bett, W., Cradock, S. Preparation of some silyl esters and study of their vibration spectra in gas and condensed phases. Monatshefte für Chemie 111, 193–198 (1980). https://doi.org/10.1007/BF00938727
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00938727