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Monatshefte für Chemie / Chemical Monthly

, Volume 111, Issue 1, pp 21–27 | Cite as

Ramanspektroskopische Untersuchungen an PCl5 II. Das System PCl5—ZrCl4

  • A. Fezâ Demiray
  • Wolfgang Brockner
Inorganic, Structural, and Physical Chemistry

Raman spectra of the system PCl5—ZrCl4

Abstract

Raman spectra of some solid and molten PCl5−ZrCl4 mixtures have been recorded. ZrCl62− complex ions accompanied by at least one more chlorozirconate species are present in the solid as well as in the melt. The newRaman frequencies are attributed to ZrCl5, which fundamentals are given and assignment is proposed to be analogous to TiCl5. The presence of ZrCl62− and ZrCl5 can be explained by the equilibrium ZrCl62−+PCl4+⇌ZrCl5+PCl5.

Keywords

Melt PCl5−ZrCl4 Raman spectra Solid 

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Copyright information

© Springer-Verlag 1980

Authors and Affiliations

  • A. Fezâ Demiray
    • 1
  • Wolfgang Brockner
    • 1
  1. 1.Anorganisch-Chemisches InstitutTechnische Universität ClausthalClausthal-ZellerfeldBundesrepublik Deutschland

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