Radical-chain oxidation of allyl alcohol by oxygen in the presence of potassium bichromate
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Potassium bichromate initiates a radical-chain oxidation of allyl alcohol. Intermediate compounds of chromium evidently participate in chain branching, reacting with hydrogen peroxide.
KeywordsOxidation Oxygen Hydrogen Alcohol Potassium
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- 1.W. Waters, Mechanism of the Oxidation of Organic Compounds [Russian translation], Mir (1966), p. 73.Google Scholar
- 2.S. H. Burnstein and H. J. Ringold, J. Amer. Chem. Soc.,89, 4722 (1967).Google Scholar
- 3.P. Müller, Helv. Chim. Acta,54, 2000 (1971).Google Scholar
- 4.A. L. Aleksandrov and E. T. Denisov, Izv. Akad. NaukSSSR, Ser. Khim., 1652 (1969).Google Scholar
- 5.E. T. Denisov, Rate Constants of Homolytic Liquid-Phase Reactions [in Russian], Nauka (1971), p. 51.Google Scholar
- 6.V. M. Solyanikov and E. T. Denisov, Neftekhimiya,6, 97 (1966).Google Scholar
- 7.N. M. Emanuel', E. T. Denisov, and Z. K. Maizus, Chain Reactions of Liquid-Phase Oxidation of Hydrocarbons [in Russian], Nauka (1965), p. 155.Google Scholar
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