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Radical-chain oxidation of allyl alcohol by oxygen in the presence of potassium bichromate

  • V. M. Solyanikov
  • N. P. Zhidkova
Physical Chemistry

Conclusions

Potassium bichromate initiates a radical-chain oxidation of allyl alcohol. Intermediate compounds of chromium evidently participate in chain branching, reacting with hydrogen peroxide.

Keywords

Oxidation Oxygen Hydrogen Alcohol Potassium 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Literature cited

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    W. Waters, Mechanism of the Oxidation of Organic Compounds [Russian translation], Mir (1966), p. 73.Google Scholar
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    A. L. Aleksandrov and E. T. Denisov, Izv. Akad. NaukSSSR, Ser. Khim., 1652 (1969).Google Scholar
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    E. T. Denisov, Rate Constants of Homolytic Liquid-Phase Reactions [in Russian], Nauka (1971), p. 51.Google Scholar
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    V. M. Solyanikov and E. T. Denisov, Neftekhimiya,6, 97 (1966).Google Scholar
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    N. M. Emanuel', E. T. Denisov, and Z. K. Maizus, Chain Reactions of Liquid-Phase Oxidation of Hydrocarbons [in Russian], Nauka (1965), p. 155.Google Scholar

Copyright information

© Consultants Bureau 1974

Authors and Affiliations

  • V. M. Solyanikov
    • 1
  • N. P. Zhidkova
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRUSSR

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