Conclusions
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1.
On the basis of a semiempirical method of calculating the structure, we calculated the NQR frequency on the35Cl nuclei in a [VOCl4]2− compound in harmony with three calculation schemes: 1) Townes-Daily, 2) taking into account the effect of the immediate environment and the Sternheimer factors, and 3) taking into account the asymmetry factor.
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2.
The nuclear quadrupole resonance spectrum was taken on the35Cl nuclei in the compound Rb2VOCl4. The experimental and theoretical values of the νNQR are found to be in agreement.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2099–2101, September, 1975.
We express gratitude to R. Abdullin for running the NQR measurements.
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Yunusov, N.B., Murav'ev, V.I. & Odintsov, B.M. Nuclear quadrupole resonance on31Cl nuclei in V4+ oxochloride. Russ Chem Bull 24, 1983–1985 (1975). https://doi.org/10.1007/BF00930181
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DOI: https://doi.org/10.1007/BF00930181