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Nuclear quadrupole resonance on31Cl nuclei in V4+ oxochloride

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    On the basis of a semiempirical method of calculating the structure, we calculated the NQR frequency on the35Cl nuclei in a [VOCl4]2− compound in harmony with three calculation schemes: 1) Townes-Daily, 2) taking into account the effect of the immediate environment and the Sternheimer factors, and 3) taking into account the asymmetry factor.

  2. 2.

    The nuclear quadrupole resonance spectrum was taken on the35Cl nuclei in the compound Rb2VOCl4. The experimental and theoretical values of the νNQR are found to be in agreement.

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Literature cited

  1. V. I. Murav'ev, N. B. Yunusov, and I. V. Ovchinnikov, Zh. Fiz. Khim.,48, 1600 (1974).

    Google Scholar 

  2. R. D. Bereman, Inorg. Chem.,11, 642 (1972).

    Google Scholar 

  3. C. H. Townes and B. R. Daily, J. Chem. Phys.,17, 782 (1949).

    Google Scholar 

  4. M. Wolfsberg and L. Helmholz, J. Chem. Phys.,20, 837 (1952).

    Google Scholar 

  5. H. Basch, A. Viste, and H. B. Gray, J. Chem. Phys.,44, 10 (1966).

    Google Scholar 

  6. J. W. Richardson, W. C. Nieupoort, R. R. Powell, and W. F. Edgell, J. Chem. Phys.,36, 1057 (1962).

    Google Scholar 

  7. J. W. Richardson, R. R. Powell, and W. C. Nieupoort, J. Chem. Phys.,38, 796 (1963).

    Google Scholar 

  8. F. Clementi, Tables of Atomic Functions, Supplement to IBM J. Res. Develop.,9, 2 (1965).

    Google Scholar 

  9. H. Basch and A. Viste, Theoret. Chim. Acta,3, 458 (1965).

    Google Scholar 

  10. T. P. Das and E. L. Hahn, Nuclear Quadrupole Resonance Spectroscopy, Academic Press, New York-London (1958).

    Google Scholar 

  11. R. Ingalls, Phys. Rev.,128, 1155 (1962).

    Google Scholar 

  12. L. O. Atovmyan and Z. G. Aliev, Zh. Struktur. Khim.,11, 728 (1970).

    Google Scholar 

  13. G. K. Semin, T. A. Babushkina, and G. G. Yakobson, Application of NQR in Chemistry [in Russian], Khimiya, Leningrad (1972), p. 224.

    Google Scholar 

  14. A. J. Freeman and R. F. Watson, Phys. Rev.,131, 2566 (1963).

    Google Scholar 

  15. P. W. Atkins and M. C. R. Symons, Structure of Inorganic Radicals, Am. Elsevier (1967).

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Authors and Affiliations

  1. Physical Technical Institute, Kazan Branch of Academy of Sciences of the USSR, USSR

    N. B. Yunusov, V. I. Murav'ev & B. M. Odintsov

Authors
  1. N. B. Yunusov
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  2. V. I. Murav'ev
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  3. B. M. Odintsov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2099–2101, September, 1975.

We express gratitude to R. Abdullin for running the NQR measurements.

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Yunusov, N.B., Murav'ev, V.I. & Odintsov, B.M. Nuclear quadrupole resonance on31Cl nuclei in V4+ oxochloride. Russ Chem Bull 24, 1983–1985 (1975). https://doi.org/10.1007/BF00930181

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  • DOI: https://doi.org/10.1007/BF00930181

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