Advertisement

Nuclear quadrupole resonance on31Cl nuclei in V4+ oxochloride

  • N. B. Yunusov
  • V. I. Murav'ev
  • B. M. Odintsov
Brief Communications
  • 15 Downloads

Conclusions

  1. 1.

    On the basis of a semiempirical method of calculating the structure, we calculated the NQR frequency on the35Cl nuclei in a [VOCl4]2− compound in harmony with three calculation schemes: 1) Townes-Daily, 2) taking into account the effect of the immediate environment and the Sternheimer factors, and 3) taking into account the asymmetry factor.

     
  2. 2.

    The nuclear quadrupole resonance spectrum was taken on the35Cl nuclei in the compound Rb2VOCl4. The experimental and theoretical values of the νNQR are found to be in agreement.

     

Keywords

Calculation Scheme Resonance Spectrum Nuclear Quadrupole Resonance Semiempirical Method Asymmetry Factor 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    V. I. Murav'ev, N. B. Yunusov, and I. V. Ovchinnikov, Zh. Fiz. Khim.,48, 1600 (1974).Google Scholar
  2. 2.
    R. D. Bereman, Inorg. Chem.,11, 642 (1972).Google Scholar
  3. 3.
    C. H. Townes and B. R. Daily, J. Chem. Phys.,17, 782 (1949).Google Scholar
  4. 4.
    M. Wolfsberg and L. Helmholz, J. Chem. Phys.,20, 837 (1952).Google Scholar
  5. 5.
    H. Basch, A. Viste, and H. B. Gray, J. Chem. Phys.,44, 10 (1966).Google Scholar
  6. 6.
    J. W. Richardson, W. C. Nieupoort, R. R. Powell, and W. F. Edgell, J. Chem. Phys.,36, 1057 (1962).Google Scholar
  7. 7.
    J. W. Richardson, R. R. Powell, and W. C. Nieupoort, J. Chem. Phys.,38, 796 (1963).Google Scholar
  8. 8.
    F. Clementi, Tables of Atomic Functions, Supplement to IBM J. Res. Develop.,9, 2 (1965).Google Scholar
  9. 9.
    H. Basch and A. Viste, Theoret. Chim. Acta,3, 458 (1965).Google Scholar
  10. 10.
    T. P. Das and E. L. Hahn, Nuclear Quadrupole Resonance Spectroscopy, Academic Press, New York-London (1958).Google Scholar
  11. 11.
    R. Ingalls, Phys. Rev.,128, 1155 (1962).Google Scholar
  12. 12.
    L. O. Atovmyan and Z. G. Aliev, Zh. Struktur. Khim.,11, 728 (1970).Google Scholar
  13. 13.
    G. K. Semin, T. A. Babushkina, and G. G. Yakobson, Application of NQR in Chemistry [in Russian], Khimiya, Leningrad (1972), p. 224.Google Scholar
  14. 14.
    A. J. Freeman and R. F. Watson, Phys. Rev.,131, 2566 (1963).Google Scholar
  15. 15.
    P. W. Atkins and M. C. R. Symons, Structure of Inorganic Radicals, Am. Elsevier (1967).Google Scholar

Copyright information

© Plenum Publishing Corporation 1976

Authors and Affiliations

  • N. B. Yunusov
    • 1
  • V. I. Murav'ev
    • 1
  • B. M. Odintsov
    • 1
  1. 1.Physical Technical InstituteKazan Branch of Academy of Sciences of the USSRUSSR

Personalised recommendations