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Acylation of dieneiron tricarbonyl complexes

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study was made of the Friedel-Crafts acylation of some iron tricarbonyl complexes with cyclic and acyclic dienes.

  2. 2.

    Transfer of the reaction center is observed in the acylation of cyclohexadieneiron tricarbonyl.

  3. 3.

    For complexes, whose structure does not prevent the formation of dienyl cations, one of the main directions of the reaction under Friedel-Crafts acylation conditions is the cleavage of hydride hydrogen.

  4. 4.

    The complex ketones were reduced by the LiAlH4-AlCl3 system.

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow

    N. S. Nametkin, A. I. Nekhaev, V. D. Tyurin & S. P. Gubin

  2. I. M. Gubkin Institute of the Petrochemical and Gas Industry, Moscow

    N. S. Nametkin, A. I. Nekhaev, V. D. Tyurin & S. P. Gubin

Authors
  1. N. S. Nametkin
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  2. A. I. Nekhaev
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  3. V. D. Tyurin
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  4. S. P. Gubin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2067–2072, September, 1975.

The authors express their gratitude to L. I. Denisovich and I. A. Suskina for running the polarographic measurements.

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Nametkin, N.S., Nekhaev, A.I., Tyurin, V.D. et al. Acylation of dieneiron tricarbonyl complexes. Russ Chem Bull 24, 1948–1953 (1975). https://doi.org/10.1007/BF00930172

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  • DOI: https://doi.org/10.1007/BF00930172

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