Skip to main content
SpringerLink
Log in

Electronic effects of silicon in phenylsilacyclobutanes

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    1-(p-X-Phenyl)-1-methylsilacyclobutanes and (p-X-phenyl)-trimethylsilanes were produced, where X=H, CH3, Cl, N(CH3)2, OCH3, CH2Si(CH3)3.

  2. 2.

    On the basis of the data on the UV spectra and the spectra of complexes with charge transfer of these compounds with tetracyanoethylene, a greater acceptor capacity of the silacyclobutyl group was detected in the ground and excited states in comparison with the trimethylsilyl groups.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. N. S. Nametkin and V. M. Vdovin, Organosilicon Compounds. Transactions of the Conference [in Russian], No. 3, NIITÉKhim (1967), p. 87.

  2. V. A. Petukhov, V. I. Zav'yalov, and V. M. Vdovin, Khimiya Geterotsikl. Soed., 164 (1968).

  3. C. S. Cundy, M. F. Lappert, J. B. Pedley, W. Schmidt, and B. T. Wilkins, J. Organometall. Chem.,51, 99 (1973).

    Google Scholar 

  4. C. G. Pitt, M. S. Habercom, M. M. Bursey, and P. F. Rogerson, J. Organometall. Chem.,15, 359 (1968).

    Google Scholar 

  5. E. M. Voigt and C. Reid, J. Amer. Chem. Soc.,86, 3930 (1964).

    Google Scholar 

  6. C. G. Pitt and H. Bock, J. Chem. Soc.,Chem. Communs., 28 (1972).

  7. L. Doub and J. M. Vandenbelt, J. Amer. Chem. Soc.,62, 2714 (1947).

    Google Scholar 

  8. R. R. Shagidullin, B. D. Chernokal'skii, I. A. Lomanova, A. S. Gel'fond, and G. Kh. Kamai, Izv. Akad. Nauk SSSR, Ser. Khim., 1490 (1969).

  9. W. Hanstein, H. J. Berwin, and T. G. Traylor, J. Amer. Chem. Soc.,82, 829 (1970).

    Google Scholar 

  10. B. A. Korolev and B. I. Stepanov, Zh. Obshch. Khim.,39, 1161 (1969).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow

    T. V. Pyatkina, V. F. Traven', É D. Babich, V. N. Karel'skii & B. I. Stepanov

  2. D. I. Mendeleev Moscow Chemicotechnologic Institute, USSR

    T. V. Pyatkina, V. F. Traven', É D. Babich, V. N. Karel'skii & B. I. Stepanov

Authors
  1. T. V. Pyatkina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. F. Traven'
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. É D. Babich
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. N. Karel'skii
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. B. I. Stepanov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1998–2002, September, 1975.

The authors are grateful to B. A. Korolev for aid in determining the values of pKa of p-substituted dimethylanilines.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Pyatkina, T.V., Traven', V.F., Babich, É.D. et al. Electronic effects of silicon in phenylsilacyclobutanes. Russ Chem Bull 24, 1879–1882 (1975). https://doi.org/10.1007/BF00930156

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00930156

Keywords

Search

Navigation