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Rate constants of reactions of peroxide radicals in methacrylic and acrylic esters undergoing oxidation

  • E. M. Pliss
  • A. L. Aleksandrov
  • M. M. Mogilevich
Physical Chemistry
  • 19 Downloads

Conclusions

  1. 1.

    Isobutyl methacrylate is oxidized according to a radical-chain mechanism with quadratic chain termination.

     
  2. 2.

    The rate constants of chain propagation and termination in methylmethacrylate, n-butyl methacrylate, isobutyl methacrylate, methyl acrylate, and n-butyl acrylate undergoing oxidation at 50 and 30° were determined.

     
  3. 3.

    The rate constants of the interaction of peroxide radicals of the monomers indicated above with phenol, α-naphthol, α- and β-naphthylamines were measured.

     

Keywords

Ester Phenol Methacrylate Acrylate Methylmethacrylate 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1976

Authors and Affiliations

  • E. M. Pliss
    • 1
    • 2
  • A. L. Aleksandrov
    • 1
    • 2
  • M. M. Mogilevich
    • 1
    • 2
  1. 1.Division of the Institute of Chemical PhysicsAcademy of Sciences of the USSRChernogolovka
  2. 2.Yaroslavl Polytechnic InstituteUSSR

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