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Rate constants of reactions of peroxide radicals in methacrylic and acrylic esters undergoing oxidation

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Isobutyl methacrylate is oxidized according to a radical-chain mechanism with quadratic chain termination.

  2. 2.

    The rate constants of chain propagation and termination in methylmethacrylate, n-butyl methacrylate, isobutyl methacrylate, methyl acrylate, and n-butyl acrylate undergoing oxidation at 50 and 30° were determined.

  3. 3.

    The rate constants of the interaction of peroxide radicals of the monomers indicated above with phenol, α-naphthol, α- and β-naphthylamines were measured.

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Authors and Affiliations

  1. Division of the Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka

    E. M. Pliss, A. L. Aleksandrov & M. M. Mogilevich

  2. Yaroslavl Polytechnic Institute, USSR

    E. M. Pliss, A. L. Aleksandrov & M. M. Mogilevich

Authors
  1. E. M. Pliss
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  2. A. L. Aleksandrov
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  3. M. M. Mogilevich
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1971–1974, September, 1975.

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Pliss, E.M., Aleksandrov, A.L. & Mogilevich, M.M. Rate constants of reactions of peroxide radicals in methacrylic and acrylic esters undergoing oxidation. Russ Chem Bull 24, 1852–1855 (1975). https://doi.org/10.1007/BF00930150

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  • DOI: https://doi.org/10.1007/BF00930150

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