Skip to main content
SpringerLink
Log in

Chain termination in the liquid-phase sulfoxidation of cyclohexane

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The kinetics of the liquid-phase sulfoxidation of cyclohexane, initiated by dicyclohexylperoxidicarbonate at 75°, was studied.

  2. 2.

    A mechanism was proposed for the process, including a reaction of the cyclohexyl radical with oxygen and of the cyclohexylsulfonyl radical with the wall of the reactor as reactions of chain termination. The relative rate constants of the reaction were determined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. R. Graf, Liebigs Ann. Chem., 50 (1952).

  2. É. E. Gilbert, Sulfonation and Related Reactions, Wiley (1965).

  3. V. D. Komissarov, M. A. Saitova, and R. F. Khalimov, Neftekhimiya,14, 270 (1974).

    Google Scholar 

  4. V. D. Komissarov, M. A. Saitova, and N. M. Vlasova, Chain Reactions of Oxidation of Hydrocarbons in the Liquid Phase [in Russian], Vol. 2 (1975), p. 105.

    Google Scholar 

  5. N. M. Émanuél', E. T. Denisov, and Z. K. Maizus, Rate Constants of Homolytic Liquid-Phase Reactions [in Russian], Nauka (1965), p. 32.

  6. L. G. Galimova, V. D. Komissarov, and E. T. Denisov, Izv. Akad. Nauk SSSR, Ser. Khim., 307 (1973).

  7. E. T. Denisov, Rate Constants of Homolytic Liquid-Phase Reactions [in Russian], Nauka (1971).

  8. B. Bjellqvist, Acta chem. scand.,27, 3180 (1973).

    Google Scholar 

  9. V. B. Kogan, V. M. Fridman, and V. V. Kafarov, Handbook on Solubility [in Russian], Vol. 1, Book 1, Izd-vo Akad. Nauk SSSR (1961).

  10. I. A. Sobolev, V. A. Kukarin, R. V. Dzhagatspanyan, V. I. Kosovorotov, P. A. Zagorets, and A. I. Popov, Khim. Prom-st', 668 (1970).

  11. V. D. Komissarov, M. A. Saitova, É. M. Kuramshin, and R. G. Timirova, Khim. Prom-st', 738 (1973).

  12. N. Basco, D. G. L. James, and F. C. James, Chem. Phys. Letters,8, 265 (1971).

    Google Scholar 

  13. F. C. James and J. A. Simons, J. Chem. Soc., Faraday Trans.,1, 2124 (1973).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemistry, Bashkir Branch of the Academy of Sciences of the USSR, Ufa

    V. D. Komissarov & R. F. Khalimov

Authors
  1. V. D. Komissarov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. R. F. Khalimov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1968–1970, September, 1975.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Komissarov, V.D., Khalimov, R.F. Chain termination in the liquid-phase sulfoxidation of cyclohexane. Russ Chem Bull 24, 1849–1851 (1975). https://doi.org/10.1007/BF00930149

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00930149

Keywords

Search

Navigation