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Influence of the structure of a paraffin hydrocarbon on the rate of its reaction with ozone

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The rates of the reaction of ozone with saturated hydrocarbons of various structures in CCl4 were studied, and the values of the rate constants for various hydrocarbons were calculated.

  2. 2.

    The rate of the reaction of ozone with n-paraffins is proportional to the number of hydrogen atoms in them, whereas, judging by the composition of the products, the probability of the insertion of ozone into a molecule is proportional to the strength of the C-H bond.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    S. D. Razumovskii, S. K. Rakovski & G. E. Zaikov

Authors
  1. S. D. Razumovskii
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  2. S. K. Rakovski
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  3. G. E. Zaikov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1963–1967, September, 1975.

In conclusion, the authors would like to express their gratitude to Doctor R. Tsvetanovich for his interest in this work and discussion of its results.

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Razumovskii, S.D., Rakovski, S.K. & Zaikov, G.E. Influence of the structure of a paraffin hydrocarbon on the rate of its reaction with ozone. Russ Chem Bull 24, 1844–1848 (1975). https://doi.org/10.1007/BF00930148

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  • DOI: https://doi.org/10.1007/BF00930148

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