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Influence of the surface on the determination of the rate constant of volume reactions of O+CO and O+Olefin

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    On a “clean” surface of a molybdenum glass vessel, molecules of CO and olefin, with which oxygen atoms present in the volume react, can be retained.

  2. 2.

    The surface reactions of O+CO and O+olefin proceed at a substantially higher rate than the volume reactions and can make a significant contribution to the determination of the value of the rate constant of the volume reaction.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    R. V. Kolesnikova & G. I. Savinova

Authors
  1. R. V. Kolesnikova
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  2. G. I. Savinova
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1957–1963, September, 1975.

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Kolesnikova, R.V., Savinova, G.I. Influence of the surface on the determination of the rate constant of volume reactions of O+CO and O+Olefin. Russ Chem Bull 24, 1838–1843 (1975). https://doi.org/10.1007/BF00930147

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  • DOI: https://doi.org/10.1007/BF00930147

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