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Oxidative transformations of 2,4-dioxo-3-(3-hydroxybutyl)-1,2,3,4,6,7-hexahyidro-11bH-benzo[a]quinolizine

  • A. A. Akhrem
  • A. M. Moiseenkov
  • V. S. Malishevskii
Organic and Biological Chemistry
  • 17 Downloads

Conclusions

The oxidation of 2,4-dioxo-3-(3-hydroxybutyl)-1,2,3,4,6,7-hexahydro-11bH-benzo[a]quinolizine with either the Sarett complex or Jones reagent gives predominantly 5-oxo-2-methyl-2,3,7,8-tetrahydro-4H,5H-benzo[a]pyrano[2,3-g]quinolizine, while oxidation with CrO3 in AcOH solution gives 8,9,14-trioxo-12-methyl-5,6,8,9,10,11,15,15a-octahydro-13-oxa-12H,14H-azepino[2,1-a]isoquinoline.

Keywords

Oxidation AcOH Isoquinoline Oxidative Transformation Jones Reagent 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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Copyright information

© Consultants Bureau 1974

Authors and Affiliations

  • A. A. Akhrem
    • 1
    • 2
  • A. M. Moiseenkov
    • 1
    • 2
  • V. S. Malishevskii
    • 1
    • 2
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRUSSR
  2. 2.Institute of Physical and Organic ChemistryAcademy of Sciences of the Belorussian SSRUSSR

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