Conclusions
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1.
A study was made of the kinetic rules for the formation of anion-radicals (AR) in the reactions of p-nitrochlorobenzene with KOH and sodium methylate. The AR of p-nitrochlorobenzene are formed in both reactions and, in addition, the AR of p-nitroanisole are formed in the reaction with CH3ONa.
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2.
It was discovered that p-nitroanisole exerts an initiating effect in the reaction of p-nitrochlorobenzene with CH3ONa.
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3.
Tetracyanoethylene and tetracyanoquinodimethane exhibit the reaction of p-nitrochlorobenzene with KOH. The scheme of a chain process was proposed for the reactions of aromatic nitro compounds with nucleophilic reagents.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1594–1601, July, 1973.
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Shein, S.M., Bryukhovetskaya, L.V. & Ivanova, T.M. Anion-radicals in reaction of p-nitrochlorobenzene with nucleophilic reagents. Russ Chem Bull 22, 1543–1549 (1973). https://doi.org/10.1007/BF00930058
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DOI: https://doi.org/10.1007/BF00930058