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Spatial structure of meldrum acid and some of its derivatives

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

On the basis of the dipole moments, Meldrum acid, its monomethyl derivatives, and 2-phenyl-1,3-dioxa-4,6-cyclohexadione in benzene solution have the bathtub conformation, while 2,2,5,5-tetramethyl-1,3-dioxa-4,6-cyclohexadione has the armchair conformation.

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Literature cited

  1. J. F. McConnell, A. McL. Mathieson, and B. P. Shoeborn, Tetrahedron Lett., 445 (1962).

  2. A. Mc L. Mathieson and J. C. Taylor, ibid., 590 (1961).

  3. K. K. Cheung, K. H. Overton, and G. A. Sim, Chem. Commun., 634 (1965); 211 (1966).

  4. R. C. Sheppard and S. Turner, ibid., 77 (1968).

  5. F. I. Carroll and J. T. Blackwell, Tetrahedron Lett., 4173 (1970).

  6. R. N. Johnson, and N. V. Riggs, Austral. J. Chem.,24, 1659 (1971).

    Google Scholar 

  7. F. I. Carroll, A, Sobti, and R. Meck, Tetrahedron Lett., 405 (1971).

  8. A. MoL. Mathieson, ibid., 81 (1963).

  9. H. Wolf, ibid., 5151 (1966).

  10. O. Korver, Tetrahedron,26, 2391 (1970).

    Google Scholar 

  11. J. Dale and S. Morgenlie, Acta Chem. Scand.,24, 2408 (1970).

    Google Scholar 

  12. P. Schuster, O. E. Polansky, and F. Wessely, Monatsh. Chem.,95, 53 (1964).

    Google Scholar 

  13. R. A. Abramovitch, Can. J. Chem.,37, 361 (1961).

    Google Scholar 

  14. R. A. Abramovitch, J. B. Rajan, and C. E. Walker, J. Chem. Engng. Data,12, 594 (1967).

    Google Scholar 

  15. J. Schuster and P. Schuster, Tetrahedron,25, 199 (1969).

    Google Scholar 

  16. M. Eigen, G. Ilgenritz, and W. Kruse, Ber.,98, 1623 (1965).

    Google Scholar 

  17. K. Pihlaja and M. Sello, Acta Chem. Scand.,22, 3053 (1968).

    Google Scholar 

  18. E. N. Gur'yanova, G. N. Ignatova, and N. I. Grishko, Zh. Strukt. Khim.,11, 665 (1970).

    Google Scholar 

  19. T. L. Hill, J. Chem. Phys.,16, 399 (1948).

    Google Scholar 

  20. E. J. Corey and R. A. Sneen, J. Am. Chem. Soc.,77, 2505 (1955).

    Google Scholar 

  21. D. Davidson and C. A. Bernhard, ibid.,70, 3426 (1948).

    Google Scholar 

  22. A. Michael and N. Weiner, ibid.,58, 680 (1936).

    Google Scholar 

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Authors and Affiliations

  1. A. M. Butlerov Chemical Institute of the V. I. Ul'yanov-Lenin Kazan State University, USSR

    E. N. Klimovitskii, L. K. Yuldasheva & B. A. Arbuzov

Authors
  1. E. N. Klimovitskii
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  2. L. K. Yuldasheva
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  3. B. A. Arbuzov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1577–1579, July, 1973.

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Klimovitskii, E.N., Yuldasheva, L.K. & Arbuzov, B.A. Spatial structure of meldrum acid and some of its derivatives. Russ Chem Bull 22, 1527–1529 (1973). https://doi.org/10.1007/BF00930054

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  • DOI: https://doi.org/10.1007/BF00930054

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