Conclusions
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1.
The existence of the dinitrate of 3,4-butanediol 1,2-oxide as a mixture of the erythro and threo isomers was confirmed on an NMR spectrometer that operated at a frequency of 200 MHz. The spectra of the individual isomers were isolated and analyzed.
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2.
We synthesized the erythro and threo isomers of 3,4-butanediol 1,2-oxide dinitrate. A study was made of the NMR spectra of these compounds and the relation between the parameters of the spectra and the structure of the diastereomers was discussed.
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3.
Some members of the partial nitrates of α-epoxy alcohols, namely the 4-nitrates of erythro- and threo-3,4-butanediol 1,2-oxide, were obtained for the first time.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1549–1554, July, 1973.
The authors thank I. S. Krainskii for his assistance in obtaining the spectra at 200 MHz.
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Lagodzinskaya, G.V., Zabrodin, V.A., Korolev, A.M. et al. Separation of signals and analysis of NMR spectra of type ABKPQY of a mixture of the erythro and threo isomers of 3,4-butanediol 1,2-oxide dinitrate on a spectrometer with an operating frequency of 200 MHz. Russ Chem Bull 22, 1502–1506 (1973). https://doi.org/10.1007/BF00930048
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DOI: https://doi.org/10.1007/BF00930048