Conclusions
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1.
A study was made of the reaction of nitrogen chlorodifluoride with the potassium salt of nitroform, cyclohexene, and vinylacetylene, at room temperature and atmospheric pressure.
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2.
It Is postulated that nitrogen chlorodifluoride is a molecular electrophilic reagent, which enters into substitution reactions by the SN2 mechanism, and can be cleaved during reaction into either ions or radicals, depending on the nature of the partner and the conditions.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1541–1544, July, 1973.
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Kosyrev, Y.M., Lapik, V.S., Bagryantsev, V.F. et al. Character of reactivity of nitrogen chlorodifluoride. Russ Chem Bull 22, 1493–1496 (1973). https://doi.org/10.1007/BF00930046
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DOI: https://doi.org/10.1007/BF00930046