Conclusions
Primary amino alcohols react with CO in the presence of mercuric acetate at 100–200° and a pressure of 100–150 atm to give the corresponding N-(hydroxyalkyl)formamides in a yield of 1.4–2.5 M/M of reacted Hg(OCOCH2)3. Morpholine under analogous conditions forms the corresponding formyl derivative and the urea derivative in a 1.2–5∶1 ratio, while cyclohexylamine forms the same derivatives in an ∼0.7 ∶1 ratio.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1533–1536, July, 1973.
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Nefedov, B.K., Sergeeva, N.S. & Eidus, Y.T. Carbonylation reaction Communication 11. Carbonylation of amino alcohols and some cyclic amines with carbon monoxide in the presence of mercuric acetate. Russ Chem Bull 22, 1486–1488 (1973). https://doi.org/10.1007/BF00930044
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DOI: https://doi.org/10.1007/BF00930044