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Telomerization of ethylene with dicarboxylic esters

  • Organic and Biological Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The diesters of mono-α-alkyl- andα,α-dialkyldicarboxylic acids were obtained by the telomerization of ethylene with the dimethyl esters of succinic and adipic acids.

  2. 2.

    Rearrangement of the radicals, with a 1,5-migration of the hydrogen atoms, occurs during the telomerization of the dimethyl ester of adipic acid.

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    A. B. Terent'ev & R. Kh. Freidlina

Authors
  1. A. B. Terent'ev
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  2. R. Kh. Freidlina
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1527–1530, July, 1973.

The authors are indebted to V. I. Dostovalova for taking and discussing the spectra.

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Terent'ev, A.B., Freidlina, R.K. Telomerization of ethylene with dicarboxylic esters. Russ Chem Bull 22, 1480–1482 (1973). https://doi.org/10.1007/BF00930042

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  • DOI: https://doi.org/10.1007/BF00930042

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