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Kinetics of the free radical interaction of methallyl chloride with CCl4, catalyzed by Fe(CO)5 or by the system Fe(CO)5-dimethylformamide

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The kinetics of the free-radical interaction of methallyl chloride with CCl4, catalyzed at 95° by iron pentacarbonyl or by the system Fe(CO)5-dimethylformamide, was studied.

  2. 2.

    A mechanism was proposed for homogeneous catalysis of the reaction, including steps of coordination of the monomer or solvent on the iron atom and transfer of a chlorine atom from the intermediate radical to the reduced form of the catalyst.

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Literature cited

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    B. A. Englin, R. D. Ismailov & R. Kh. Freidlina

Authors
  1. B. A. Englin
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  2. R. D. Ismailov
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  3. R. Kh. Freidlina
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1498–1504, July, 1973.

The authors are grateful to É. G. Rozantsev for kindly providing the nitroxide-free radicals.

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Englin, B.A., Ismailov, R.D. & Freidlina, R.K. Kinetics of the free radical interaction of methallyl chloride with CCl4, catalyzed by Fe(CO)5 or by the system Fe(CO)5-dimethylformamide. Russ Chem Bull 22, 1455–1460 (1973). https://doi.org/10.1007/BF00930037

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  • DOI: https://doi.org/10.1007/BF00930037

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