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Influence of the rate constants of certain elementary oxidation reactions on the value of the synergistic effect in the action of mixtures of inhibitors

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A mathematical analysis was made of the influence of the rate constants of the elementary reactions characterizing various substrates of oxidation on the value of the synergistic effect under the action of mixtures of inhibitors.

  2. 2.

    The dependence of the value of the synergistic effect on the change in the rate constants of reactions of chain propagation k2, chain branching k3, and chain propagation by the inhibitor radical k10 was considered.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, USSR

    M. Ya. Meskina, G. V. Karpukhina & Z. K. Maizus

Authors
  1. M. Ya. Meskina
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  2. G. V. Karpukhina
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  3. Z. K. Maizus
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1481–1488, July, 1973.

The authors would like to thank A. V. Krestinin and M. Ya. Gol'denberg for compiling the program used in the calculations.

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Meskina, M.Y., Karpukhina, G.V. & Maizus, Z.K. Influence of the rate constants of certain elementary oxidation reactions on the value of the synergistic effect in the action of mixtures of inhibitors. Russ Chem Bull 22, 1440–1445 (1973). https://doi.org/10.1007/BF00930034

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  • DOI: https://doi.org/10.1007/BF00930034

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