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Chemiluminescence in the reaction of carbohydrates with ethylenimine derivatives

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The chemiluminescence in reactions, of N-acetylethylenimine with various carbohydrates and polyols was investigated, and the influence of the structure of the carbohydrate on the chemiluminescence intensity was established.

  2. 2.

    The reaction of ethylenimine with carbohydrates is accompanied by chemiluminescence as a result of oxidation of the glycoside carbon atom by oxygen.

  3. 3.

    During the reaction of 2-deoxy-D-ribose with N-acetylethylenimine, H2O2 is formed, the kinetic characteristics of the formation of which coincide with the kinetics of chemiluminescence.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, USSR

    D. L. Lashkova, G. P. Troitskaya, K. E. Kruglyakova & N. M. Emanuel'

Authors
  1. D. L. Lashkova
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  2. G. P. Troitskaya
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  3. K. E. Kruglyakova
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  4. N. M. Emanuel'
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1478–1480, July, 1973.

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Lashkova, D.L., Troitskaya, G.P., Kruglyakova, K.E. et al. Chemiluminescence in the reaction of carbohydrates with ethylenimine derivatives. Russ Chem Bull 22, 1436–1439 (1973). https://doi.org/10.1007/BF00930033

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  • DOI: https://doi.org/10.1007/BF00930033

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