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Interaction of tantalum halides with lithium aluminum hydride in ether

  • Inorganic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    In the interaction of tantalum halides with lithium aluminum hydride, regardless of the ratio of the initial components, tantalum tetraaluminum hydride Ta(AlH4)4 is formed; during the reaction it already decomposes, eliminating aluminum hydride and forming products of variable composition TaHn(AlH4)4−n.

  2. 2.

    The solubility of tantalum and lithium chlorides at room temperature and that of their bromides in the interval −70 to +25° were determined. When tantalum pentabromide is treated with ether, it is reduced.

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, USSR

    A. I. Golovanova, M. E. Kost & V. I. Mikheeva

Authors
  1. A. I. Golovanova
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  2. M. E. Kost
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  3. V. I. Mikheeva
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1448–1452, July, 1973.

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Golovanova, A.I., Kost, M.E. & Mikheeva, V.I. Interaction of tantalum halides with lithium aluminum hydride in ether. Russ Chem Bull 22, 1410–1413 (1973). https://doi.org/10.1007/BF00930027

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  • DOI: https://doi.org/10.1007/BF00930027

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