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Reaction of nitrates of monovalent cations with BCl3

  • K. V. Titova
  • V. Ya. Rosolovskii
Brief Communications

Conclusions

  1. 1.

    The reactions of BCl3 in CCHCl3 with MNO3 (M=K, Rb, Cs, (CH3)4N, (C2H5)4N, (C4H9)4N) proceed slowly at 20° and are accompanied by decomposition of the NO 3 ion. The degree of decomposition increases with increase in the size of the cation.

     
  2. 2.

    It was established that M[Cl3BONO2] and M[B(ONO2)4] are formed as intermediate compounds; one of the intermediate products (C2H5)4N[B(ONO2)4] was isolated and identified. The final solid reaction products contain MBCl4.

     

Keywords

Nitrate Intermediate Product Intermediate Compound Monovalent Cation BCl3 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Plenum Publishing Corporation 1976

Authors and Affiliations

  • K. V. Titova
    • 1
  • V. Ya. Rosolovskii
    • 1
  1. 1.Institute of New Chemical ProblemsAcademy of Sciences of the USSRChernogolovka

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