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Mechanism of the oxygen disproportionation of ditert-alkylniteoxyl radicals

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reactions of acid disproportionation of piperidinooxyls and the interaction of 1-oxo with 1-hydroxypiperidinium salts are reversible and proceed through an intermediate 1-hydroxypiperidmylium cation according to a general kinetic scheme.

  2. 2.

    The rate and equilibrium constants were determined for the reaction of acid disproportionation of 2,2,6,6-tetramethylpiperidino-1-oxyl.

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Authors and Affiliations

  1. Division of the Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka

    V. A. Golubev, V. D. Sen', I. V. Kulyk & A. L. Aleksandrov

Authors
  1. V. A. Golubev
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  2. V. D. Sen'
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  3. I. V. Kulyk
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  4. A. L. Aleksandrov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2235–2243, October, 1975.

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Golubev, V.A., Sen', V.D., Kulyk, I.V. et al. Mechanism of the oxygen disproportionation of ditert-alkylniteoxyl radicals. Russ Chem Bull 24, 2119–2126 (1975). https://doi.org/10.1007/BF00929736

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  • DOI: https://doi.org/10.1007/BF00929736

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