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Enthalpies of hydration of anions of certain organic dithioacids and comparison of the stability of complex compounds with these anions in gas and in solution

  • S. V. Larionov
  • T. I. Koroleva
  • I. M. Cheremisina
Physical Chemistry
  • 33 Downloads

Conclusions

  1. 1.

    The enthalpies of solutions of C2H5OCS2K, (C2H5O)2 PS2K, and (C2H5)2NCS2Na in water were determined at 25°.

     
  2. 2.

    The enthalpies of hydration of the anions (C2H5O)2PS 2 , C2H5OCS 2 s- , and (C2H5)2NCS 2 .

     
  3. 3.

    The order of variation of the stability of complexes of metals with these dithioanions in the gas and in solution is the same.

     

Keywords

Hydration Enthalpy Complex Compound 
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Copyright information

© Plenum Publishing Corporation 1976

Authors and Affiliations

  • S. V. Larionov
    • 1
  • T. I. Koroleva
    • 1
  • I. M. Cheremisina
    • 1
  1. 1.Institute of Inorganic Chemistry, Siberian BranchAcademy of Sciences of the USSRNovosibirsk

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