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Kinetics and mechanism of the epoxidation of olefins by hydroper oxides in the presence of molybdenum compounds

Communication 2. Solubility of propylene in ethylbenzene at increased pressures
  • V. A. Gavrilenko
  • E. I. Evzerikhin
  • I. I. Moiseev
Physical Chemistry

Conclusions

The solubility of propylene in ethylbenzene was investigated at 5–36 atm and 60–120°. Under the indicated conditions the solubility is proportional to the pressure. The logarithm of the equilibrium constant of the solubility is a linear function of the reciprocal of the temperature. The heat of solution of propylene in ethylbenzene practically coincides with the heat of evaporation of liquid propylene.

Keywords

Oxide Evaporation Propylene Molybdenum Linear Function 
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Literature cited

  1. 1.
    V. A. Gavrilenko, E. I. Evzerikhin, V. A. Kolosov, G. M. Larin, and I. I. Moiseev, Izv. Akad. Nauk SSSR, Ser. Khim., 1954 (1974).Google Scholar
  2. 2.
    Yu. I. Kozorezov and T. S. Novozhilova, Khim. Prom-st',56, 434 (1971).Google Scholar

Copyright information

© Plenum Publishing Corporation 1976

Authors and Affiliations

  • V. A. Gavrilenko
    • 1
  • E. I. Evzerikhin
    • 1
  • I. I. Moiseev
    • 1
  1. 1.N. S. Kurnakov Institute of General and Inorganic ChemistryAcademy of Sciences of the USSRMoscow

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