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Reaction of bis(tetraethyl)alanates of alkaline-earth metals with halogens and aluminum halides

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study was made of the reaction of the bis(tetraethyl)alanates of the alkaline-earth metals with bromine, iodine, and aluminum halides.

  2. 2.

    The metal-carbon bonds in alanate complexes of type M[Al(C2H5)4]2 are more reactive than in triethylaluminum itself.

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Literature cited

  1. L. I. Zakharkin and V. V. Gavrilenko, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 166 (1959).

  2. V. K. Golubev, Dissertation [in Russian], Moscow (1971).

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  4. P. Shützenberger, Ann. Chem.,167, 86 (1873).

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  5. T. Talalaeva and K. A. Kocheshkov, Methods in Heteroorganic Chemistry. Li, Na, K, Rb, and Cs [in Russian], Vol. 2, Nauka (1971), p. 583.

  6. L. L. Ivanov, S. Ya. Zavizion, and L. I. Zakharkin, Zh. Obshch. Khim.,43, 2254 (1973).

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    L. L. Ivanov, S. Ya. Zavizion & L. I. Zakharkin

Authors
  1. L. L. Ivanov
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  2. S. Ya. Zavizion
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  3. L. I. Zakharkin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1619–1620, July, 1974.

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Ivanov, L.L., Zavizion, S.Y. & Zakharkin, L.I. Reaction of bis(tetraethyl)alanates of alkaline-earth metals with halogens and aluminum halides. Russ Chem Bull 23, 1540–1541 (1974). https://doi.org/10.1007/BF00929675

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  • DOI: https://doi.org/10.1007/BF00929675

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