Conclusions
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1.
Dichlorocarbene selectively adds to the double bond of the methyl ether of dimethylvinylethynylcarbinol.
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2.
The ozonization and oxidation of the methyl ether of gem-dichlorocyclopropyldimethylethynylcarbinol leads to a mixture of the gem-dichlorocyclopropanecarboxylic andα-methoxyisobutyric acids.
Literature cited
L. P. Danilkina and I. A. D'yakonov, Zh. Organ. Khim.,2, 3 (1966).
L. Vo-Quang and P. Cadiot, Compt. Rend.,252, 3827 (1961).
I. A. D'yakonov and L. P. Danilkina, Zh. Obshch. Khim.,34, 738 (1964).
E. V. Dehmlow, Chem. Ber.,101, 410, 427 (1968).
H. Weitkamp, U. Hasserodt, and F. Korte, Chem. Ber.,95, 2280 (1962).
L. J. Bellamy, Infrared Spectra of Complex Molecules [Russian translation], IL, Moscow (1963).
J. W. Emsley, J. Feeney, and L. H. Sutcliffe, High Resolution Nuclear Magnetic Resonance Spectroscopy [Russian translation], Vol. 2, Mir (1969).
C. Weizmann, M. Sulzbacher, and E. Bergmann, J. Am. Chem. Soc.,70, 1153 (1948).
A. L. Barker and G. S. Skinner, J. Am. Chem. Soc.,46, 407 (1924).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1613–1615, July, 1974.
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Retinskii, A.A., Borodin, L.I., Keiko, V.V. et al. Reaction of dichlorocarbene with methyl ether of dimethylvinylethynylcarbinol. Russ Chem Bull 23, 1535–1536 (1974). https://doi.org/10.1007/BF00929673
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DOI: https://doi.org/10.1007/BF00929673