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Effect of heteroatom in aliphatic sulfur- and oxygen-containing compounds on the values of the retention indices in gas chromatography

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    It was found that an analogy exists in the gas chromatographic behavior of aliphatic sulfur- and oxygen-containing compounds. Equations were proposed that relate the retention indices of the corresponding compounds.

  2. 2.

    A study was made of the effect of the character of the heteroatom on the values of the retention indices of mercaptans and alcohols, and also of sulfides and ethers, on columns packed with Apiezon M, Triton X-305, and polyethylene glycol-1000.

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Literature cited

  1. W. O. McReynolds, Gas Chromatographic Retention Data, Preston Technical Abstract Co., Evanston. Illinois (1966).

    Google Scholar 

  2. Gas Chromatographic Data Compilation, A. S. T. M., New York (1968).

  3. E. Kováts and A. B. Weisz, Ber. Bunsenges, Phys. Chem.,69, 812 (1965).

    Google Scholar 

  4. G. C. Pimentel and A. L. McClellan, The Hydrogen Bond [Russian translation], Mir (1964), pp. 41, 170, 174.

  5. B. V. Aivazov, S. M. Petrov, V. R. Khairullina, and V. G. Yapryntseva, Physicochemical Constants of Organosulfur Compounds [in Russian], Khimiya (1964).

  6. E. Kovats, Helv. Chim. Acta,41, 1915 (1958).

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    R. V. Golovnya & V. G. Garbuzov

Authors
  1. R. V. Golovnya
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  2. V. G. Garbuzov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1599–1601, July, 1974.

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Golovnya, R.V., Garbuzov, V.G. Effect of heteroatom in aliphatic sulfur- and oxygen-containing compounds on the values of the retention indices in gas chromatography. Russ Chem Bull 23, 1519–1521 (1974). https://doi.org/10.1007/BF00929667

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  • DOI: https://doi.org/10.1007/BF00929667

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