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Determination of position of sulfate groups in sulfurizedmonosac charides

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A new method was developed for the mild removal of sulfo groups from the fully acetylated sulfates of monosaccharides using thionyl chloride.

  2. 2.

    A chemical method was proposed for determining the positions of the sulfo groups in sulfurized monosaccharides, which consists in desulfurizing the acetyl derivatives and subsequent methylation.

  3. 3.

    The acetyl groups in the acetyl derivatives of the pyridinium salts of various sulfates of D-glucose do not migrate under solvolytic desulfurization conditions.

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Literature cited

  1. D. L. Cook, B. Eich, and P. S. Cammarata, Arch. Intern. Pharmacodyn.,144, 1 (1963).

    Google Scholar 

  2. K. K. Takemoto and S. S. Spicer, Ann. New York Acad. Sci.,130, 365 (1965).

    Google Scholar 

  3. J. P. McKinell and E. Percival, J. Chem. Soc., 3141 (1962).

  4. A. I. Usov, K. P. Adamyants, L. I. Miroshnikova, A. A. Shaposhnikova, and N. K. Kochetkov, Carbohyd. Res.,18, 336 (1971).

    Google Scholar 

  5. M. L. Wolfrom and R. Montgomery, J. Am. Chem. Soc.,72, 2859 (1950).

    Google Scholar 

  6. A. I. Usov, L. I. Miroshnikova, and N. K. Kochetkov, Zh. Obshch. Khim.,42, 945 (1972).

    Google Scholar 

  7. J. R. Turvey, Advan. Carbohyd. Chem.,20, 183 (1965).

    Google Scholar 

  8. N. K. Kochetkov, A. I. Usov, and L. I. Miroshnikova, Zh. Obshch. Khim.,40, 2475 (1970).

    Google Scholar 

  9. S. Hirase and K. Watanabe, Bull. Chem. Soc. Japan,45, 1629 (1972).

    Google Scholar 

  10. J. O. Deferrari, E. G. Cros, and I. O. Mastronardi, Carbohyd. Res.,4, 432 (1967).

    Google Scholar 

  11. B. Helferich, Chem. Ber.,95, 2604 (1962).

    Google Scholar 

  12. E. A. Talley, Methods in Carbohydrate Chemistry [Russian translation], Mir (1967), p. 177.

  13. B. Helferich, Ann. Chem.,455, 173 (1927).

    Google Scholar 

  14. S. Peat, D. M. Bowker, and J. R. Turvey, Carbohyd. Res.,7, 225 (1968).

    Google Scholar 

  15. R. L. Whistler, W. W. Spencer, and G. N. Bemiller, Methods in Carbohydrate Chemistry [Russian translation], Mir (1967), p. 156.

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Authors and Affiliations

  1. Pacific Ocean Institute of Bioorganic Chemistry, Far Eastern Scientific Center of Academy of Sciences of the USSR, Vladivostok

    A. F. Pavlenko, N. I. Belogortseva, A. I. Kalinovskii & Yu. S. Ovodov

Authors
  1. A. F. Pavlenko
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  2. N. I. Belogortseva
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  3. A. I. Kalinovskii
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  4. Yu. S. Ovodov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1593–1596, July, 1973.

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Pavlenko, A.F., Belogortseva, N.I., Kalinovskii, A.I. et al. Determination of position of sulfate groups in sulfurizedmonosac charides. Russ Chem Bull 23, 1513–1515 (1974). https://doi.org/10.1007/BF00929665

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  • DOI: https://doi.org/10.1007/BF00929665

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