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Condensed heteroaromatic systems that contain a thiophene ring

Communucation 28. Metalation of selenopheno[3,2-b]thiophene

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    When selenopheno[3,2-b]thiophene is metalated with n-butyllithium the lithium attacks theα-position of both the selenophene and thiophene fragments of the molecule.

  2. 2.

    Based on the data of the competing metalation reaction, the following order in the relative reactivity of the studied compounds was derived: selenopheno[3,2-b]thiophene > thieno [3,2-b]thiophene>selenophene>thiophene.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    V. P. Litvinov, I. P. Konyaeva & Ya. L. Gol'dfarb

Authors
  1. V. P. Litvinov
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  2. I. P. Konyaeva
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  3. Ya. L. Gol'dfarb
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Additional information

See [1] for Communication 27.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1575–1579, July, 1974.

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Litvinov, V.P., Konyaeva, I.P. & Gol'dfarb, Y.L. Condensed heteroaromatic systems that contain a thiophene ring. Russ Chem Bull 23, 1493–1496 (1974). https://doi.org/10.1007/BF00929660

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  • DOI: https://doi.org/10.1007/BF00929660

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