Alkylation of isoparaffin hydrocarbons with olefins on zeolite catalysts

Communication 2. Alkylation of isobutane with 1-butene, isobutylene, and 2-methyl-2-butene
  • E. S. Mortikov
  • S. M. Zen'kovskii
  • N. V. Mostovoi
  • N. F. Kononov
  • L. I. Golomshtok
  • Kh. M. Minachev
Organic and Biological Chemistry

Conclusions

A study was made of the alkylation of isobutane with 1-butene, a mixture of n-butenes, isobutylene, and 2-methyl-2-butene in the presence of zeolite catalysts at 100° and a pressure of 20 atm. In contrast to acids, the alkylation of n-butanes with butylenes proceeds on zeolite catalysts. The “autoalkylation” reaction also takes place, the same as in the presence of acid catalysts.

Keywords

Zeolite Hydrocarbon Alkylation Acid Catalyst Isobutylene 

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Literature cited

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    E. S. Mortikov, S. M. Zen'kovskii, N. V. Mostovoi, Kh. M. Minachev, N. F. Kononov, L. I. Golomshtok, and S. S. Kurdyumov, Khim. i Tekhnol. Topliv i Masel, 13 (1974).Google Scholar
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    A. Z. Dorogochinskii, A. V. Lyuter, and E. G. Vol'pova, Sulfuric Acid Alkylation of Isoparaffins with Olefins [in Russian], Khimiya (1970), p. 142.Google Scholar
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Copyright information

© Plenum Publishing Corporation 1975

Authors and Affiliations

  • E. S. Mortikov
    • 1
  • S. M. Zen'kovskii
    • 1
  • N. V. Mostovoi
    • 1
  • N. F. Kononov
    • 1
  • L. I. Golomshtok
    • 1
  • Kh. M. Minachev
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRMoscow

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