Conclusions
-
1.
An axial orientation of the As-Cl bond in 2-chloro-1,3,2-dioxaarsolanes was established by the method of dipole moments.
-
2.
On the basis of the Kerr constants we determined the geometrical configuration of the substituents in 4-methyl- and meso-4,5-dimethyl-2-chloro-1,3,2-dioxaarsolanes.
-
3.
For the dioxaarsolanes studied, substantial deviations from an additive scheme of the polarizabilities are observed.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
A. N. Vereshchagin, S. G. Vul'fson, and B. A. Arbuzov, Izv. Akad. Nauk SSSR, Ser. Khim., 1029 (1974).
O. A. Osipov and V. I. Minkin, Handbook of Dipole Moments [in Russian], Vysshaya Shkola (1985).
R. J. W. Le Fevre, A. Sundaram, and R. K. Rierens, J. Chem. Soc., 479 (1963).
R. J. W. Le Fevre, Adv. in Physical Organic Chemistry,3, 1 (1965).
Tables of Interatomic Distances and Configurations, L. E. Sutton (editor), London (1958).
V. A. Naumov, N. M. Zaripov, and V. G. Dashevskii, Dokl. Akad. Nauk SSSR,188, 1962 (1969).
D. W. Aksnes and O. Vikane, Acta Chem. Scand.,26, 835 (1972).
V. A. Naumov and N. M. Zaripov, Zh. Strukturnoi Khimii,2, 1108 (1970).
J. P. Casey and K. Mislow, Chem. Commun., 999 (1970).
D. W. Aksnes and O. Vikane, Acta Chem. Scand.,26, 2532 (1972).
F. P. Boer and J. J. Flynn, J. Amer. Chem. Soc.,91, 6604 (1969).
H. F. van Woerden and E. Havinga, Recueil Trav. Chim.,86, 341 (1967).
M. J. Aroney, G. M. Hoskins, R. J. W. Le Fevre, R. K. Rierens, and D. V. Radford, Austral J, Chem.,22, 2243 (1969).
M. L. Kemp and R. J. W. Le Fevre, J. Chem. Soc., 3463 (1965).
C. G. Le Fevre and R. J. W. Le Fevre, Rev. Pure Appl. Chem.,5, 261 (1955).
G. Kamai and Z. L. Khisamova, Dokl. Akad. Nauk SSSR,76, 535 (1951).
G. Kamai and Z. L. Khisamova, Zh. Obshch. Khimii,24, 816 (1954).
H. Funk and H. Köhler, J. Prakt. Chem.,13, 322 (1961).
M. Kohn, J. Amer. Chem. Soc.,73, 480 (1951).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1512–1517, July, 1974.
Rights and permissions
About this article
Cite this article
Arbuzov, B.A., Yuldasheva, L.K., Anonimova, I.V. et al. Dipole moments and molar kerr constants of certain 2-chloro-1,3,2-dioxaarsolanes. Russ Chem Bull 23, 1433–1437 (1974). https://doi.org/10.1007/BF00929646
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00929646