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The photochemical reduction of mixed acidodiammines of Pt(IV)

  • A. G. Samatov
  • N. N. Zheligovskaya
  • V. I. Spitsyn
Inorganic Chemistry
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Conclusions

  1. 1.

    The compounds (NH3)2NO2Cl3Pt, (NH3)2NO2ClBrClPt, (NH3)2NO2ClBr2Pt, (NH3)2NO2Br3Pt were synthesized, and their behavior in aqueous solutions was studied by UV spectra, pH measurements, and electric conductivity.

     
  2. 2.

    The instability of aqueous solutions of the synthesized compounds in the light was established.

     
  3. 3.

    A possible mechanism of the transition of Pt(IV) compounds to Pt(II) compounds was discussed. A hypothesis was advanced on the equilibrium nature of the photoreduction reaction.

     

Keywords

Aqueous Solution Electric Conductivity Photochemical Reduction Equilibrium Nature Photoreduction Reaction 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    I. I. Chernyaev, Izv. In-ta po Izucheniyu Platiny IONKh AN SSSR,5, 102 (1927).Google Scholar
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    I. I. Chernyaev, G. S. Muraveiskaya, and L. S. Korablina, Zh. Neorgan. Khimii,11, 1365 (1966).Google Scholar
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    I. I. Chernyaev and G. S. Muraveiskaya, Izv. Sektora Platiny IONKh AN SSSR,25, 35 (1950).Google Scholar
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    Yu. N. Kukushkin, Zh. Neorgan. Khimii,6, 1098 (1961).Google Scholar
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    A. G. Samatov, N. N. Zheligovskaya, and Vikt. I. Spitsin, Izv. Akad. Nauk SSSR, Ser. Khim., 274 (1974).Google Scholar

Copyright information

© Plenum Publishing Corporation 1975

Authors and Affiliations

  • A. G. Samatov
    • 1
  • N. N. Zheligovskaya
    • 1
  • V. I. Spitsyn
    • 1
  1. 1.M. V. Lomonosov Moscow State UniversityUSSR

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