Intramolecular exchange of trimethylsilyl group in trimethylsilylesters of nitronic acids

  • S. L. Ioffe
  • V. M. Shitkin
  • B. N. Khasapov
  • M. V. Kashutina
  • V. A. Tartakovskii
  • M. Ya. Myagi
  • É. T. Lippmaa
Brief Communications

Conclusions

  1. 1.

    A study was made of the1H,13C,14N, and29Si NMR spectra of some trimethylsilyl esters of nitronic acids.

     
  2. 2.

    A rapid intramolecular exchange of the trimethylsilyl group between the oxygen atoms of the O −N(O) fragment was observed.

     

Keywords

Oxygen Ester Oxygen Atom Trimethylsilyl Trimethylsilyl Group 

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Literature cited

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    É. T. Lippmaa, M. Ya. Myagi, M. V. Kashutina, S. L. Ioffe, and V. A. Tartakovskii, Izv. Akad. Nauk SSSR, Ser. Khim., 188 (1972).Google Scholar
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Copyright information

© Consultants Bureau 1974

Authors and Affiliations

  • S. L. Ioffe
    • 1
  • V. M. Shitkin
    • 1
  • B. N. Khasapov
    • 1
  • M. V. Kashutina
    • 1
  • V. A. Tartakovskii
    • 1
  • M. Ya. Myagi
    • 1
  • É. T. Lippmaa
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRUSSR

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