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2-fluoro-2,2-dinitroethyl chloeomethyl ether in nucleophilic substitution reactions

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

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It was shown that 2-fluoro-2,2-dinitroethyl chloromethyl ether has a high reactivity in nucleophilic substitution reactions, and a number of esters and derivatives of 4-fluoro-4,4-dinitro-2-oxa-1-butanol was obtained.

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Literature cited

  1. H. G. Adolph and M. J. Kamlet, J. Org. Chem.,34, 45 (1969).

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  2. L. T. Eremenko, F. Ya. Natsibullin, G. V. Oreshko, and G. N. Nesterenko, Izv. Akad. Nauk SSSR, Ser. Khim., 2556 (1970).

  3. N. Kornblum, in: Organic Reactions, Vol. 12 [Russian translation], IL (1965), p. 117.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2140–2141, September, 1973.

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Oreshko, G.V., Romanova, L.B. & Eremenko, L.T. 2-fluoro-2,2-dinitroethyl chloeomethyl ether in nucleophilic substitution reactions. Russ Chem Bull 22, 2091–2092 (1973). https://doi.org/10.1007/BF00929417

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  • DOI: https://doi.org/10.1007/BF00929417

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