Conclusions
The esters of methyl-substitutedα,β-thioglycsdic acids have the same inversion of the exit as the corresponding ester derivatives. The elution order is determined by the intramolecular reaction of the carbomethoxyl groups with the substituents. The obtained data can be used to confirm the structures of the studied compounds.
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Literature cited
M. G. Lin'kova, L. P. Parshina, O. V. Kil'disheva, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim., 2413 (1968).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2139–2140, September, 1973.
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Golovnya, R.V., Garbuzov, V.G. Effect of intramolecular reaction on elution of methyl α,β- thioglycidates in gas chromatography. Russ Chem Bull 22, 2089–2090 (1973). https://doi.org/10.1007/BF00929416
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DOI: https://doi.org/10.1007/BF00929416