Effect of intramolecular reaction on elution of methyl α,β- thioglycidates in gas chromatography
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The esters of methyl-substitutedα,β-thioglycsdic acids have the same inversion of the exit as the corresponding ester derivatives. The elution order is determined by the intramolecular reaction of the carbomethoxyl groups with the substituents. The obtained data can be used to confirm the structures of the studied compounds.
KeywordsMethyl Ester Chromatography Ester Derivative Elution Order
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