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Effect of intramolecular reaction on elution of methyl α,β- thioglycidates in gas chromatography

  • R. V. Golovnya
  • V. G. Garbuzov
Brief Communications
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Conclusions

The esters of methyl-substitutedα,β-thioglycsdic acids have the same inversion of the exit as the corresponding ester derivatives. The elution order is determined by the intramolecular reaction of the carbomethoxyl groups with the substituents. The obtained data can be used to confirm the structures of the studied compounds.

Keywords

Methyl Ester Chromatography Ester Derivative Elution Order 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Literature cited

  1. 1.
    M. G. Lin'kova, L. P. Parshina, O. V. Kil'disheva, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim., 2413 (1968).Google Scholar
  2. 2.
    L. P. Parshina, M. G. Lin'kova, O. V. Kil'disheva, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim., 931 (1970).Google Scholar
  3. 3.
    W. O. McReynolds, Gas Chromatographic Retention Data, Preston Technical Abstracts Co., Evanston, Illinois (1966).Google Scholar

Copyright information

© Consultants Bureau 1974

Authors and Affiliations

  • R. V. Golovnya
    • 1
  • V. G. Garbuzov
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRUSSR

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