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Use of labeled14C carbon monoxide to study the formation of methane in the catalytic hydropolymerization of ethylene initiated by carbon monoxide

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

By using radioactive carbon monoxide it was shown that in the initial step of the reaction for the hydropolymerization of ethylene in the presence of hydrogen, initiated by carbon monoxide, at 190°, the formation of methane is the result of the hydrocracking of ethylene or of the hydrocarbons derived from it.

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Literature cited

  1. G. V. Isagulyants, N. I. Ershov, Yu. I. Derbentsev, and Ya. T. Éidus, Izv. Akad. Nauk SSSR, Ser. Khim., 1234 (1968).

  2. Ya. T. Éidus, N. I. Ershov, K. V. Puzitskii, and I. V. Guseva, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk: 913 (1960).

  3. Yu. I. Derbentsev, G. V. Isagulyants, L. F. Rar, D. L. Pakul', and A. A. Balandin, Dokl. Akad. Nauk SSSR,177, 1371 (1967).

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    G. V. Isagulyants, N. I. Ershov, N. N. Rozhdestvenskaya, Chong Yem Hoang, Yang Yung Ping & Ya. T. Éidus

Authors
  1. G. V. Isagulyants
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  2. N. I. Ershov
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  3. N. N. Rozhdestvenskaya
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  4. Chong Yem Hoang
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  5. Yang Yung Ping
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  6. Ya. T. Éidus
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2126–2127, September, 1973.

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Isagulyants, G.V., Ershov, N.I., Rozhdestvenskaya, N.N. et al. Use of labeled14C carbon monoxide to study the formation of methane in the catalytic hydropolymerization of ethylene initiated by carbon monoxide. Russ Chem Bull 22, 2072–2073 (1973). https://doi.org/10.1007/BF00929409

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  • DOI: https://doi.org/10.1007/BF00929409

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