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Initiated oxidation of cyclohexyl methyl ether and the role of the hydroxyl group of the alcohol in the regeneration of oxidation inhibitors

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The rate constants of initiation (azoisobutyrodinitrile), chain propagation and termination were measured in the initiated oxidation of cyclohexyl methyl ether (CHME).

  2. 2.

    The rate constants and coefficients of inhibition in a medium of CHME undergoing oxidation were measured for five inhibitors of different classes at 70°.

  3. 3.

    The reducing properties ofα-hydroxyperoxide radicals of alcohols are due to the hydrogen atom of the hydroxyl group.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, USSR

    G. A. Kovtun & A. L. Aleksandrov

Authors
  1. G. A. Kovtun
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  2. A. L. Aleksandrov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1946–1950, September, 1973.

The authors would like to express their deep gratitude to E. T. Denisov for his attention to the work.

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Kovtun, G.A., Aleksandrov, A.L. Initiated oxidation of cyclohexyl methyl ether and the role of the hydroxyl group of the alcohol in the regeneration of oxidation inhibitors. Russ Chem Bull 22, 1897–1900 (1973). https://doi.org/10.1007/BF00929371

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  • DOI: https://doi.org/10.1007/BF00929371

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