Conclusions
The opening of S-arylepisulfonium complexes that are isobutylene derivatives proceeds with the exclusive formation of the Markovnikov adducts.
This is a preview of subscription content, log in via an institution to check access.
Literature cited
G. H. Schmid and D. G. Garratt, “Electrophilic additions to carbon-carbon double bonds,” in: The Chemistry of Double Bonded Functional Groups (ed. by S. Patai), Wiley, New York (1977).
G. H. Schmid and D. G. Garratt, Can. J. Chem.,51, 2463 (1973).
W. H. Mueller and P. E. Butler, J. Am. Chem. Soc.,90, 2075 (1968).
W. A. Smit, A. S. Gybin, V. S. Bogdanov, M. Z. Krimer, and É. A. Vorob'eva, Tetrahedron Lett.,12, 1085 (1978).
A. S. Gybin, M. Z. Krimer, V. A. Smit, V. S. Bogdanov, and É. A. Vorob'eva, Izv. Akad. Nauk SSSR, Ser. Khim.,1978, 510.
G. Olah, P. Westerman, E. Melby, and Y. Mo, J. Am. Chem. Soc.,96, 3565 (1974).
M. Oki, W. Nakanishi, M. Fukunaga, G. Smith, W. Duax, and Y. Osawa, Chem. Lett.,1975, 1277.
Y. Kikuzono, T. Yomabe, S. Nagata, H. Kato, and K. Fukui, Tetrahedron,30, 2197 (1974).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2156–2160, September, 1978.
Rights and permissions
About this article
Cite this article
Gybin, A.S., Smit, V.A., Bogdanov, V.S. et al. Regiospecific markovnikov opening of 1,1-dimethyl-S-arylepisulfonium ions by nucleophiles. Russ Chem Bull 27, 1905–1908 (1978). https://doi.org/10.1007/BF00929255
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00929255