Conclusions
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1.
The hydrosilylation of alkyl phenyl ketones and cyclohexanone with phenyldhnethylsilane, catalyzed by hydrorhodiumcarboranes, gives a mixture of the silyl and vinyl silyl ethers, whose ratio depends on the nature of the solvent and on the structure of the ketone and hydrorhodiumcarborane.
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2.
The addition of triethylamine when catalysis is by hydrorhodiumcarboranes leads to an increase in the amount of the corresponding vinyl silyl ether.
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Literature cited
T. E. Rakhen and M. F. Hawthorne, J. Am. Chem. Soc.,96, 4674 (1974).
L. I. Zakharkin and T. B. Agakhanova, Izv. Akad. Nauk SSSR, Ser. Khim.,1977, 2632.
L. I. Zakharkin, I. V. Pisareva, and T. B. Agakhanova, Izv. Akad. Nauk SSSR, Ser. Khim.,1977, 2389.
J. Ojima and M. Nihonyanagi, J. Chem. Soc. Chem. Commun.,1972, 938.
J. Ojima, T. Kogure, M. Nihonyanagi, and J. Nagai, Bull. Chem. Soc. Jpn.,45, 3506 (1972).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2151–2153, September, 1978.
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Zakharkin, L.I., Agakhanova, T.B. Hydrosilylation of ketones with phenyldimethylsilane, catalyzed by hydrorhodiumcarboranes. Russ Chem Bull 27, 1900–1902 (1978). https://doi.org/10.1007/BF00929253
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DOI: https://doi.org/10.1007/BF00929253